11H-Dibenzo[b,e]azepine-6-carbonitrile

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11H-Dibenzo[b,e]azepine-6-carbonitrile

The title compound, C(15)H(10)N(2), crystallizes with two independent mol-ecules in the asymmetric unit. The two benzene rings make dihedral angles of 60.32 (2) and 61.35 (3)°. The crystal packing is stabilized by weak π-π stacking inter-actions [centroid-to-centroid distances = 3.673 (4) and 3.793 (4) Å].

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6′-Amino-3′-methyl-11H,2′H-spiro­[indeno­[1,2-b]quinoxaline-11,4′-pyrano[2,3-c]pyrazole]-5′-carbonitrile ethanol monosolvate

In the title spiro-indeno-quinoxaline compound, C(22)H(14)N(6)O·C(2)H(6)O, the five-membered ring of the indene unit and the pyran ring are perpendicular [89.11 (3)°]. In the crystal, N-H⋯N hydrogen bonds connect the spiro-indeno-quinoxaline mol-ecules, and the ethanol solvent mol-ecules complete the hydrogen-bond network via O-H⋯N and N-H⋯O inter-actions.

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2-Amino-6-methyl-4,5,6,7-tetra­hydro-1-benzothio­phene-3-carbonitrile

In the title compound, C(10)H(12)N(2)S, one of the C atoms of the cyclo-hexene ring (at position 6) and the methyl group attached to it are disordered over two sets of sites in a 0.650 (3):0.350 (3) ratio. The cyclo-hexene ring in both the major and minor occupancy conformers adopts a half-chair conformation. The thio-phene ring is essentially planar (r.m.s. deviation = 0.05 Å). In the crystal,...

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6-Meth­oxy-2-methyl-1-phenyl-1H-indole-3-carbonitrile

In the title compound, C(17)H(14)N(2)O, the dihedral angle between the indole ring system and the phenyl ring is 64.48 (7)°. The crystal packing features weak C-H⋯π inter-actions.

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2-Eth­oxy-4-(4-methyl­phen­yl)-6-phenyl­pyridine-3-carbonitrile

The title compound, C(21)H(18)N(2)O, crystallized with two independent mol-ecules (A and B) in the asymmetric unit. In mol-ecule A, the central pyridine ring forms dihedral angles of 14.55 (13) and 39.14 (12)° with the terminal phenyl and benzene rings, respectively. The latter rings make a dihedral angle of 33.06 (13)° with each other. The corresponding values for mol-ecule B are 26.86 (13), 4...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808033072